Ammonia nitrogen sewage wastewater treatment plant
USD $6,500 - $75,360.5 /Set
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Shandong Jinhaosanyang Environmental Protection Machine Co., Ltd.
Ammonia nitrogen sewage wastewater treatment plant
To strip the basic principle of the method is will air ventilation with waste water, wastewater and the volatile gases dissolved in the liquid to solute gas phase, make the waste water treatment process called get blown off. Be to remove material in liquid and gas phase difference is the concentrations of the liquid into the gas phase by driving force. To remove the basic principle of the method is gas liquid balance and mass transfer speed theory.
Used to remove ammonia nitrogen removal from the water, is the gas into the water, contentious mutual fully contact with liquid, make the water dissolved free ammonia gas and liquid through the interface, to gas phase transfer, so as to achieve the purpose of removing ammonia nitrogen.
The water of ammonia nitrogen, mostly with ammonium ion (NH4 +) and free ammonia (NH3) the state of balance and exist. The balance equation is as follows:
NH4++OH-NH3+H2O (1)
Ammonia and ammonium ion of distribution between rate is calculated under the available type:
Ka=Kw /Kb=(CNH3·CH+)/CNH4+ (2)
In equation:
Ka——Ammonium ion of ionization constants;
Kw——Water ionization constants;
Kb——Ammonia water ionization constants;
C——Matter concentration.
Equation(1)is influenced by PH value, when high pH value, the balance to the right move, free ammonia larger proportion, when pH value for about 11, free ammonia roughly 90%.
By equation (2) can see, pH value is the effect of free ammonia water percentage in one of the major factors. In addition, the temperature can also affect reactive (1) balance, temperature, balance to move right. Table 1 lists the different conditions of ammonia nitrogen the calculated value of the dissociation rate. The data show that, when pH value is more than 10, dissociation rate at 80% or more, when the pH value of 11, dissociation rate is as high as 98% and subject to the influence of the temperature of little.
Different pH, temperature of ammonia nitrogen dissociation rate %, see the table below:
pH | 20°C | 30°C | 35°C |
9.0 | 25 | 50 | 58 |
9.5 | 60 | 80 | 83 |
10.0 | 80 | 90 | 93 |
11.0 | 98 | 98 | 98 |