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Description:Antioxidant is a substance added in small quantities to hydrocarbons which are susceptible
to oxidation, such as rubbers, plastics, foods, and oils to inhibit or
slow oxidative processes, while being itself oxidized. Antioxidants work in two
different ways. In primary antioxidants (also called free-radical scavengers),
antioxidative activity is implemented by the donation of an electron or hydrogen
atom to a radical derivative. These antioxidants are usually hindered amines (p-Phenylene
diamine, trimethyl dihydroquinolines, alkylated diphenyl amines) or
substituted phenolic compounds with one or more bulky functional groups such as
a tertiary butyl at 2,6 position commonly. Butylated hydroxytoluene (BHT) is a common
example of hindered phenolic antioxidant. The reaction rate, or carbocation
stability, in SN1 mechanism is 3